Just some data I've had to compile while working, thought it's be nice to just have it somewhere if anyone else needs it (The copy Table as Image button isn't working too well right now, might fix once I understand javascript a bit more). The Export to Excel button downloads an excel sheet that doesn't include the images, sorry about that :/.
Author | Catalyst | Pressure/Temperature | Time (hr.) | % Conversion | TON | TOF (hr-1) |
---|---|---|---|---|---|---|
Fryzuk | R[P2N2]-NbCH2SiMe3(R = Ph, Cy) |
500 psi, Room Temp. | 20 hours | 9.75 % | 225 | 11.25 hr-1 |
Fortier | (η6-ImDippN)(Xyketguan)Ti |
150 psi, 80 °C | 60 hours | N/A | 2.0 | 0.05 hr-1 |
Marks | ZrS/Cp*ZrMe2 |
1 atm, 25 °C | 1 hour | 10 % | 1200 | 1200 hr-1 |
ZrCp*Me3+B(C6F5)3 |
1 atm, 25 °C | 1 hour | 0.24 % | 1.4 | 1.4 hr-1 | |
Rothwell (Supported) | [Ti(CH2SiMe3)4] on Silica | 1200-1400 psi, 120 °C | 6 hours | 39 % | 1.4 | 1.4 hr-1 |
[Zr(CH2Ph)4] on Silica | 1200-1400 psi, 120 °C | 5 hours | 100 % | 4000 | 800 hr-1 | |
[Hf(CH2Ph)4] on Silica | 1200-1400 psi, 120 °C | 12 hours | 100 % | 4000 | 400 hr-1 | |
[Nb2(μ2-CSiMe3)2(CH2SiMe3)4] on Silica | 1200-1400 psi, 120 °C | 4 hours | 100 % | 4000 | 1000 hr-1 | |
[Nb2(μ2-CSiMe3)2(CH2SiMe3)4] on Silica | 1200-1400 psi, 120 °C | 10 hours | 100 % | 4000 | 333 hr-1 | |
[Ta(CH2C6H4-Me-4)5] on Silica | 1200-1400 psi, 120 °C | 24 hours | 32 % | 320 | 53 hr-1 | |
[Mo2(CH2SiMe3)6] on Silica | 1200-1400 psi, 120 °C | 5 hours | 2 % | 96 | 16 hr-1 | |
Rothwell (Molecular) | [Nb(OC6HPh4-2,3,5,6)2Cl3]/3nBuLi |
1200 psi, 120 °C | 6 hours | 40 % | 164 | 27.3 hr-1 |
Muetterties | CH3C6H5TiAl2Cl8 |
1 atm, 125 °C | 10 hours | 10 % | N/A | N/A |
My Work | Can't say till it's published :P | Can't say till it's published :P | Can't say till it's published :P | Can't say till it's published :P | Can't say till it's published :P | Can't say till it's published :P |