Table of Literature Values

Early Transition Metal Arene Hydrogenation (Specifically Benzne)

Just some data I've had to compile while working, thought it's be nice to just have it somewhere if anyone else needs it (The copy Table as Image button isn't working too well right now, might fix once I understand javascript a bit more). The Export to Excel button downloads an excel sheet that doesn't include the images, sorry about that :/.



Author Catalyst Pressure/Temperature Time (hr.) % Conversion TON TOF (hr-1)
Fryzuk
R[P2N2]-NbCH2SiMe3(R = Ph, Cy)
500 psi, Room Temp. 20 hours 9.75 % 225 11.25 hr-1
Fortier
(η6-ImDippN)(Xyketguan)Ti
150 psi, 80 °C 60 hours N/A 2.0 0.05 hr-1
Marks
ZrS/Cp*ZrMe2
1 atm, 25 °C 1 hour 10 % 1200 1200 hr-1

ZrCp*Me3+B(C6F5)3
1 atm, 25 °C 1 hour 0.24 % 1.4 1.4 hr-1
Rothwell (Supported) [Ti(CH2SiMe3)4] on Silica 1200-1400 psi, 120 °C 6 hours 39 % 1.4 1.4 hr-1
[Zr(CH2Ph)4] on Silica 1200-1400 psi, 120 °C 5 hours 100 % 4000 800 hr-1
[Hf(CH2Ph)4] on Silica 1200-1400 psi, 120 °C 12 hours 100 % 4000 400 hr-1
[Nb22-CSiMe3)2(CH2SiMe3)4] on Silica 1200-1400 psi, 120 °C 4 hours 100 % 4000 1000 hr-1
[Nb22-CSiMe3)2(CH2SiMe3)4] on Silica 1200-1400 psi, 120 °C 10 hours 100 % 4000 333 hr-1
[Ta(CH2C6H4-Me-4)5] on Silica 1200-1400 psi, 120 °C 24 hours 32 % 320 53 hr-1
[Mo2(CH2SiMe3)6] on Silica 1200-1400 psi, 120 °C 5 hours 2 % 96 16 hr-1
Rothwell (Molecular)
[Nb(OC6HPh4-2,3,5,6)2Cl3]/3nBuLi
1200 psi, 120 °C 6 hours 40 % 164 27.3 hr-1
Muetterties
CH3C6H5TiAl2Cl8
1 atm, 125 °C 10 hours 10 % N/A N/A
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